Jason Shearer

Educated at: University of Maryland, University of Washington

Occupation: chemist, university teacher

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Synthetic Models for Metalloenzymes Containing Sulfur-metal Bonds

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Articles 33

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September 21, 2016

The Hexahistidine Motif of Host-Defense Protein Human Calprotectin Contributes to Zinc Withholding and Its Functional Versatility

Jason Shearer
November 17, 2015

A Redox-Active, Compact Molecule for Cross-Linking Amyloidogenic Peptides into Nontoxic, Off-Pathway Aggregates: In Vitro and In Vivo Efficacy and Molecular Mechanisms

Jason Shearer, Kyle J Korshavn, Brandon T. Ruotolo, Ayyalusamy Ramamoorthy
June 12, 2015

Subtle Modulation of Cu4X4L2 Phosphine Cluster Cores Leads to Changes in Luminescence

Jason Shearer, Vincent J. Catalano
April 27, 2015

An Air‐ and Water‐Tolerant Zinc Hydride Cluster That Reacts Selectively With CO2

Vincent J. Catalano, Jason Shearer, David M Ermert, Leslie J Murray
April 16, 2015

Adiabaticity of the proton-coupled electron-transfer step in the reduction of superoxide effected by nickel-containing superoxide dismutase metallopeptide-based mimics,Adiabaticity of the Proton-Coupled Electron-Transfer Step in the Reduction of Superoxide Effected by Nickel-Containing Superoxide Dismutase Metallopeptide-Based Mimics

Jason Shearer
January 16, 2015

A nickel phosphine complex as a fast and efficient hydrogen production catalyst

Jason Shearer, Vladimiro Mujica
September 1, 2014

Formation and structure of two luminescent salts of [Au(SCSN3)2]−obtained through the [2 + 3] cyclization of carbon disulfide and azide ion

Jason Shearer, Marilyn M Olmstead
May 13, 2014

Insight into the structure and mechanism of nickel-containing superoxide dismutase derived from peptide-based mimics,Insight into the Structure and Mechanism of Nickel-Containing Superoxide Dismutase Derived from Peptide-Based Mimics

Jason Shearer
March 1, 2014

The novel hydrogen-rich binuclear cobalt complex anion, [(CoH3)2H3]5−

Jason Shearer, Jerod M Kieser
September 21, 2013

Dioxygen and superoxide stability of metallopeptide based mimics of nickel containing superoxide dismutase: the influence of amine/amidate vs. bis-amidate ligation,Dioxygen and superoxide stability of metallopeptide based mimics of nickel containing superoxide dismutase: The influence of amine/amidate vs. bis-amidate ligation

Jason Shearer
June 1, 2013

Dioxygen mediated conversion of {Fe(NO)2}9 dinitrosyl iron complexes to Roussin's red esters

Jason Shearer
May 1, 2013

Copper ligation to soluble oligomers of the English mutant of the amyloid-β peptide yields a linear Cu(I) site that is resistant to O2 oxidation,Copper ligation to soluble oligomers of the English mutant of the amyloid-β peptide yields a linear Cu(i) site that is resistant to O2 oxidation

Jason Shearer, Kristy L Peck
January 22, 2013

Use of a metallopeptide-based mimic provides evidence for a proton-coupled electron-transfer mechanism for superoxide reduction by nickel-containing superoxide dismutase,Use of a Metallopeptide‐Based Mimic Provides Evidence for a Proton‐Coupled Electron‐Transfer Mechanism for Superoxide Reduction by Nickel‐Containing Superoxide Dismutase

Jason Shearer
January 9, 2013

Crystallographic and Computational Studies of Luminescent, Binuclear Gold(I) Complexes, AuI2(Ph2P(CH2)nPPh2)2I2(n= 3–6)

Jason Shearer, Marilyn M Olmstead, Jian-Hua Jia, James C Fettinger
January 18, 2012

Modulation of luminescence by subtle anion-cation and anion-π interactions in a trigonal Au(I)···Cu(I) complex,Modulation of Luminescence by Subtle Anion–Cation and Anion−π Interactions in a Trigonal AuI···CuI Complex

Jason Shearer, Vincent J. Catalano
January 20, 2011

One octarepeate expansion to the human prion protein alters both the Zn2+ and Cu2+ coordination environments within the octarepeate domain

Jason Shearer
January 18, 2011

Phenol nitration induced by an {Fe(NO)2}(10) dinitrosyl iron complex

Jason Shearer
November 8, 2010

Cu K-edge X-ray absorption spectroscopy reveals differential copper coordination within amyloid-β oligomers compared to amyloid-β monomers

Jason Shearer
October 1, 2010

Use of metallopeptide based mimics demonstrates that the metalloprotein nitrile hydratase requires two oxidized cysteinates for catalytic activity,Use of Metallopeptide Based Mimics Demonstrates That the Metalloprotein Nitrile Hydratase Requires Two Oxidized Cysteinates for Catalytic Activity

Jason Shearer
August 1, 2010

A modular approach to redox-active multimetallic hydrophobes of discoid topology,A Modular Approach to Redox-Active Multimetallic Hydrophobes of Discoid Topology

Jason Shearer, Marco M Allard, Maurício Lanznaster
June 1, 2010

Bisamidate and mixed amine/amidate NiN2S2 complexes as models for nickel-containing acetyl coenzyme A synthase and superoxide dismutase: an experimental and computational study

Jason Shearer
December 1, 2009

Luminescent copper(I) halide butterfly dimers coordinated to [Au(CH3imCH2py)2]BF4 and [Au(CH3imCH2quin)2]BF4.

Jason Shearer, Vincent J. Catalano
November 1, 2009

Metallopeptide based mimics with substituted histidines approximate a key hydrogen bonding network in the metalloenzyme nickel superoxide dismutase

Jason Shearer
December 1, 2008

Influence of sequential guanidinium methylation on the energetics of the guanidinium...guanine dimer and guanidinium...guanine...cytosine trimer: implications for the control of protein...DNA interactions by arginine methyltransferases

Jason Shearer
December 1, 2008

The amyloid-beta peptide of Alzheimer's disease binds Cu(I) in a linear bis-his coordination environment: insight into a possible neuroprotective mechanism for the amyloid-beta peptide

Jason Shearer
August 6, 2008

Both Met(109) and Met(112) are utilized for Cu(II) coordination by the amyloidogenic fragment of the human prion protein at physiological pH.

Jason Shearer
April 10, 2008

Diversity, function and evolution of genes coding for putative Ni-containing superoxide dismutases

Jason Shearer
March 11, 2008

Probing variable amine/amide ligation in Ni(II)N2S2 complexes using sulfur K-edge and nickel L-edge X-ray absorption spectroscopies: implications for the active site of nickel superoxide dismutase

Jason Shearer
November 7, 2007

Probing variable axial ligation in nickel superoxide dismutase utilizing metallopeptide-based models: insight into the superoxide disproportionation mechanism

Jason Shearer
January 2006

Synthesis, characterization, and crystal structure of a quadruply bonded dimolybdenum(II) complex containing the water-soluble phosphine 1,3,5-triaza-7-phosphaadamantane (PTA)

Brian J. Frost, Jason Shearer
April 1, 2005

Substrate oxidation by copper-dioxygen adducts: mechanistic considerations

Jason Shearer
January 1, 2003

Tuning copper-dioxygen reactivity and exogenous substrate oxidations via alterations in ligand electronics

Jason Shearer

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Author

Jason Shearer

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Works 1

Synthetic Models for Metalloenzymes Containing Sulfur-metal Bonds

Articles 33

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